Anillación de Danheiser
La anillación o ciclización de Danheiser es una reacción orgánica en donde se obtiene un trialquilsililciclopenteno en una ciclización regiocontrolada por la acción de una cetona α, β-insaturada y un trialquilsililaleno (por ejemplo, trimetilsilil o triisopropilsililoxifurano) en presencia de un ácido de Lewis.[1][2][3][4][5][6]
Referencias[editar]
- ↑ "TMS-Cyclopentene Annulation: A Regiocontrolled Approach to the Synthesis of Five-Membered Rings", R. L. Danheiser, D. J. Carini, and A. Basak, J. Am. Chem. Soc. 1981, 103, 1604.
- ↑ "Scope and Stereochemical Course of the (Trimethylsilyl)cyclopentene Annulation", R. L. Danheiser, D. J. Carini, D. M. Fink, and A. Basak, Tetrahedron 1983, 39, 935.
- ↑ "The Reaction of Allenysilanes with α,β-Unsaturated Acylsilanes: New Annulation Approaches to Five and Six-Membered Carbocyclic Compounds", R. L. Danheiser and D. M. Fink, Tetrahedron Lett. 1985, 26, 2513.
- ↑ "A General [3+2] Annulation: cis-4-Exo-isopropenyl-1,9-dimethyl-8-(trimethylsilyl)bicyclo-[4.3.0]non-8-en-2-one", R. L. Danheiser, D. M. Fink, and Y. -M. Tsai, Organic Syntheses 1988, 66, 8.
- ↑ "Organic Syntheses Based on Name Reactions", By Alfred Hassner and C. Stumer, Elsevier, p. 78, 2002
- ↑ "Name Reactions: A Collection of Detailed Reaction Mechanisms", By Jie Jack Li, Springer, p. 102, 2003
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Datos: Q1057963